Hi Vipers, first of all, I'm sure you'll enjoy your new system; the Bryston/PMC combo is very synergistic.
With regards to amplification, a 7B or 14B2 amp will definitely be a nice step up from a single 4B, and would probably be preferable to running a pair of bridged 4Bs. However, this obviously entails selling your brand new amp, which is a hassle after all that effort.
Purchasing a good source/pre-amp and getting room acoustics/speaker positioning right is a better spend than getting a second amp for a passive speaker. You've already taken care of the first by getting the BCD-1/BP26. However, if (and this is a big if) you have a reasonably sized, acoustically ok room and don't want to swap the 4B for a 7, I would say that adding a second amp as a horizontal (stereo) bi-amp will probably add more resolution, dynamic "bite" and ease to your system's presentation (or so I would like to imagine as far as my own system goes). The theory is that dedicating one amp to the bass will take the load off the second one on the mid/tweet and hence result in lower overall distortion for both amps; however, I'm no scientist at this, it's all hearsay, and passive bi-amping is more of a 'touchy feely' area. Many PMC owners do seem to prefer bi or tri-amping, so why not get a 3B or 4B on a loaner and judge for yourself?
Let us know how your system comes together; I'm coincidentally also awaiting delivery of my new BP26, and will be happy to play around with bi-amping and let you know my thoughts once i get my system back up and running again. Good luck.