My placement of speaker and chair is typically the following:
Speakers are in a corner, and are 1.5 feet away from the "side" walls at the closest point to the speaker. There are bookshelves "behind" the speakers, leading to the gear that is placed centrally in the corner.
They are about 6 feet apart from each other.
My chair tends to be 6-10 feet away from the plane of the speakers.
Pic being worth 1000 words... here is a slightly aged pic, and the chair is not there.

