The Player - Thomas Newman
25th Hour - Terrence Blanchard
Thin Red Line - Hans Zimmer
101 Dalmations (The old version, loved it as a kid)
The Sound of Music
Rock & Roll High School - Ramones & Others
Koyaanisqatsi, Powaqqatsi, Naqoyqatsi - Philip Glass
The Road Warrior - Brian May
There Will Be Blood - Jonny Greenwood
The Cook, The Thief, His Wife & Her Lover - Michael Nyman (Plus his other work on Peter Greenaway films is great)
Then there's also a lot of movies with good collections of hits, more than an original score.
Jim C