I apologize for my slow response.
I must first admit that I am not an amplifier designer. While I can easily recognize the Williamson push-pull design in several different forms, it would take me considerable work to design an amplifier starting with nothing. Some modifications are easily within my grasp, but I leave the thicker stuff for those who are enthusiastic about this stuff. I am a speaker-guy at heart.
However, the linear gain curve (mu) for any tube is reasonably easy to read with some study. In this regard, if a tube is pushed to swing a greater distance for greater gain there will be more distortion. In my opinion, an EL34 has a reasonable output of 30wpc in a push-pull configuration. If you wish to have more output while using only a pair of tubes, I suggest a design using KT-88 tubes.
Secondly, i was rather disappointed in the availability of high quality electrolytics for the power supply. All the old classics seem obsolete, and I'd like to keep the cost to under $20 a piece. The only decent option I've found so far in that range is a pair of Evox Rifa's at 470uf 450V for the first set.
Unfortunately, most good products have a commensurate price tag

. Occasionally there are bargains in any realm, but I don't know of any in the capacitor realm. The good stuff is more expensive. There is a reasonably summary of electrolytic capacitors here:
http://www.tnt-audio.com/clinica/ssps3_e.html. Aside from this, Black Gate does make a 100uf 500v capacitor. There are also some slightly larger metallized poly capacitors from Angela or SCR. But... this stuff isn't cheap (or small). Also, for a power supply, you could certainly cascade bypass some less expensive electrolytics, and use metalized poly for the smaller values.
I do admire you desire to build a tube amplifier. Everyone knows that tubes sound better

.
I do have 2 solid suggestions in this realm. Neither may be welcome, but they are my opinion.
1. Buy a kit from someone where you can obtain good support. // I believe this is one reason why Hugh Dean (AKSA) does very well).
or
2. Buy something you can tweak. There are plenty of Dynaco mod projects available. I own a modified ST70, and it sounds VERY good.
I again apologize for my slow response. Hopefully you find some of this helpful.
Dave