Thanks for the comprehensive information Mike - things are starting to make a bit more sense for a beginner like me. Part of what I didn't realise is the plans is that the radius is the radius of the round-over, so I'll make sure that it gets done an the back of the woofer.
I'm going to try my luck and keep asking questions - if I'm being a pain feel free to ignore them

While the plans don’t call for a roundover on the outside of the front baffle, sharp corners can cause reflection issues so I usually put at least a 3/8” roundover on the vertical edges of the front baffle.
My earlier description wasn’t really clear on this. You pretty much want the size of the roundover to match the thickness of the hardwood. What you are trying to accomplish is have the roundover end at the seam betweenthe front baffle and the side. This makes a nice clean transition.
Is my understanding correct that you are talking about the outside facing vertical of the front-baffle? I would never have imagined that this could affect the sound - I would have assumed that the enclosed parts affect it more so just want to make sure.
If the overall width of the finished baffle is more than what the plans call for, it will affect the baffle step loss. The roundovers mitigate this by reducing the effective width of the baffles. If the width is a little bit off you should be OK.
Ok, even though I don't know what step-loss is, the width makes sense. Because you laminated a thick piece of wood on the side, you had to reduce the overall width of the front baffle and the rounded edges achieves that.

As you can see, using this technique requires some up front planning and attention to detail on how you need to modify the plans and/or edge profile to end up with proper dimensions both internally and externally.
Absolutely. To add a bit to the confusion, in South Africa we use the metric system and I can't get my hands on 3/4" MDF (works out to 19.05mm). 16mm and 22mm is readily available. It now looks like I can probably get 18mm. I have planned to ensure that the inner dimensions are exact, but sounds like the outer should also be. Which is more important, or should I do it half/half? Gut feel is still inner is more important.
While building to the plan specs with MDF then veneering is a beginner to intermediate level project, doing a custom milled hardwood laminate like I did is an advanced project requiring specialized equipment and skills whether you use hand tools, machines, or a combination. In my case I have a band saw with a 12” resaw capacity, a 15” helical head planer, and a 16/32” drum sander. These are the machines I used to take the 10’ long, 8/4 rough cut board down to the finished pieces I used in the build.
Yup - fully agree with this point and wouldn't really dream of doing it myself. I have a buddy that has lots of equipment and experience and I'll discuss it with him. I'll probably end up going with the standard MDF build ... but I absolutely LOVE the look of real hardwood, and maybe in time I can build another box.
Again, thanks for your input and for yours, @hawkeyejw - much appreciated.