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Well... when electricity first sees a circuit or a capacitor it doesn't have what's called an "electron memory". Once an electron finds a path it wants to keep finding that path because it knows that it's easy to follow, it's the path of least resistance. So it memorizes that path. It's the same reason you sometimes see a spark unplugging a lamp from the wall, the electrons still want to flow through that path.
Your brain does the same thing... it's called muscle memory. Electrical signals firing in the brain without you having to think about it actively. But you're not born with certain abilities, you develop muscle memory as you practice them.
When your brain tells your arm to move it's sending an electrical signal through your nerves to trigger the muscle to flex in a certain way. The more you do that certain action the faster and easier it becomes.The same thing occurs with capacitors... it's still electrical signals. They flow for a certain purpose. The more they flow to that point the easier a time they have "getting there".
Electrical signals are electrical signals.
Nobody has an explanation that will satisfy an audiophile and an engineer simultaneously.Hope that helps