Traditional use is to flatten the impedence curve on a woofer. Typical woofers have significant rise with frequency, the Zobel makes it a flat line, and allows the network to function correctly as frequency rises. But there are many other uses for Zobel like networks, I use one in my Cirrus on the AudioTechnology woofer which has effectively NO inductive rise. It's function there isn't to flatten impedance since it's already flat, but to adjust the woofer rolloff in order to meet target which then aligns phase between woofer and tweeter.
A Zobel on the tweeter can be used to flatten the peak at the Resonance Frequency, also called a trap in this application. On tweeters you basically try the network with and without, listen closely and see if there's any benefit.
Many times speakers that should have a Zobel on the woofer don't because of extra cost, same with the tweeter.