I got some more listening in over the past couple of nights, just movies off the PVR. I plan to do more listening with CDs and probably some SACD's and DVD-A's this weekend along with Rio on Blu-Ray. I'm still noticing that the bass has more punch but it's not as obvious when watching movies. That may be because the sound was in legacy Dolby Diigital or simply because all of the speakers in the surround system were active and not just the 802 Diamonds. I'll probably be able to answer that by the end of the weekend.
As for the mids and highs, there is no real stand out difference like with the bass, if I heard any change it would be that the speakers appear to breathe better and seem more open as if in a larger room and separated further than they actually are. I definitely didn't have any moments like OMG the highs are now so clear and the mids so smooth, etc., etc. I find the 802 Diamonsd incredibly clear and articulate anyways so there probably wasn't a lot to gain here. I'm sure for most normal listening the tweeter gets used the least with the mids and bass drivers seeing the most activity and it would stand to reason that the bass drivers, in my case 2 8" drivers would benefit more from having 300 watts to their own than the single 6.5" mid driver would.