You either made error in the process of measurements or have rather big mistakes in stuffing the PCB. I assume you power the Piccolo from a DC PS 15V. Lets look at your measurements:
C20 14.63v; U2 Pin 4 14.52
is actually the same points - OK.
U2 Pin 2 0; Pin 3 0; U1 pins 3 and 6 -- zero
All this points tied to the ground - OK.
U2 Pin 1 1.3v; R22 1.3v
is actually (5.5/4.3)*1=1.27V - OK
Pin5 5.57; C21 5.58v
the same points - OK.
C3 200mv
This is already wrong. It seems the R12, S2 or D4 could be out of service, but...
C7 70mv and C9 14.5v and C18 78mv
totally puzzled me - as soon as it is on the same rail I can't imagine where the 14.5V on C9 and the voltage for...
The LED still lights up.
comes from?
The rest of the measurements doesn't really of any need because of that.
I think you should carefully check your PCB and find maybe solder bridge or mistakes, bare wires, shorting a circuit...
Then, please explain what exactly was the sound (and where the sound comes from - the Piccolo, your acustic systems or...)?