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Keep in mind most tubes need 100 hours on them to sound their best.
I listen to a tube for a while, then switch to another, then back, each a week or so at a time. I try to notice things I like and things I don't like about each. I don't listen for anything in particular, but just let the ideas come to me. Sometimes a tube sounds good off the bat, but I discover annoying attributes after a while. Also, changing to a lower distortion tube will uncover faults in other parts of the system. A clearer sounding tube is not always the best answer, although it is an opportunity to fix the other parts to achieve higher overall performance. Some people use tubes to add more distortion and cover up problems, while others use them for the potential for low tonal and spatial errors. Don't put too much faith in other peoples' opinions about a particular tube that you read online. You have to buy the tube, break it in and listen to it in your own system to know anything about it. The same tube will sound different in a different amp circuit. You have to give a tube 50-100 hours before you can judge it. It will sound completely different up and down several times before it finally settles. Some tubes need even longer. My GT E34Ls tubes need 400 hours before they are finally stable. It's all fun until you realize you're insane, then back to solid state for a while.