As always, I have more questions with regards to woodworking. I am learning slowly. I am needing to get up the learning curve on two topics and would love help from those in the know.
1) I'd really love to do a black baffle on a veneered cabinet. For the life of me I can't see how this is as simple as some make it look. It seems the only practical way is to finish after cabinet assembly. In this case how do you keep the area seperated? Is taping off the veneer really enough to ensure the paint doesn't bleed into it?
Example

2) I have aspiration to make the back two vertical corners 45º angles. Like Duke's beautiful creations

(I want to do this on the back, not the front, but same concept). What is the best/easiest way to make these types of joints? 22.5º locking miter? Flush joint? Built around a "frame"?
My track record with 45º flush joints isn't inspiring. There always seems to be some distortion of he joint when completing the box, either due to not quite 45º, not perfectly square pieces or warping of the boards. My last attempt was better than the first couple but this was a much smaller scale.