Just a slight expansion on Tom's suggestion. What I do on my scope is set my scope to 'AC coupled' (which puts a capacitor is series with the signal) and center the image. Then by pressing the 'DC coupling' button you able to rapidly switch back between the 2 and visually see the amount of dc offset. If you've a scope with multimeter functions, which many PC based USB scopes have, you can simply measure the mean voltage which is the dc offset (assuming your mains is reasonably close to a sine)
PS - the better Fluke multimeters can directly read the dc offset on a AC signal