Jules,
Measure it. You'll need a test cd with a constant tone and a voltmeter of some sort that can measure RMS voltage at audio frequencies. (I finally broke down and bought a usb based digital storage oscilloscope which have all sorts of these capabilities, the NZ based Cleverscope)
Measure the output voltage from the NAD while playing the specific single tone, single level track. Vo. Put a resistor, R, across the output and measure the voltage across that resistor, Vr, while playing that same track. 5k Ohm should work well; enough to put some load on the output device, but not enough to fry it.
By Ohm's Law -
Zo = R (Vo -Vr) / Vr
I use the stereophile test cd, but you can download test tones at various levels off the net and burn your own test cd.
EDIT - the current Nad 542 is specified as having a 150 ohm output impedance, so I'd imagine that Nad specified the 5420 similarly. FWIW