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Apple lossless saves about 40-50% space on the disc; it is a perfect copy (like a zip file). Some folks, including myself, claim they can occasionally hear some sonic differences between wav and a compressed lossless file like FLAC, but I assume it's mainly in the processing/decoding overhead, and I don't hear it often. Net/net, I doubt you'll hear anything that will keep you from Apple Lossless, assuming you need to save the disc space. If space is not an issue (on an iPod it clearly would be), then just rip to wav (16 bit, stereo, 44k) and let er rip.