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How do you measure what he's hearing? It's not a tube/SS factor... so, now what? He just has to decide what he likes best and go with it. What if it is a measureable item? Who's going to standardize the spec to always include it? No one.
You folks make too much out of this. Tubes are the most linear devices that we can use. However, they are not made in a complementary way, so we have to couple the tube stages with transformers or caps. This is a compromise that solid state can design around. However, fets and bipolar transistors have more higher order distortion, because their transfer function is not as linear as a tube. The distortion produced can be reduced in all amps with negative feedback, but that creates other problems, too complex to describe here ...
BTW, it is precisely because of the linearity of the tube that we can design 'romance' into it. You do that by manipulating operating points and plate loading, and when you design for the lowest possible distortion with tubes, you finish with a sound very like good SS, at least in terms of detail and accuracy. ...
Where do my SS power amps fall? A Forté 4 class A and a pair of Marantz Ma-5 Esotec class A or B monoblocks? They do have outstanding midrange, lack of grain and effortless presentation with lots of depth...