I'll post details here as I progress in case anyone else is interested. The parts are a single GR M-165x, Vifa XT25TG30-04, and .75cu/ft Parts Express box. I'll be running these sealed, since the 165x needs more volume to gain any significant extension vented - and sealed they'll be easy to integrate with a sub, or would make good surrounds.
One pair of speakers are mounted in the cabinet, below are the results I got measuring the drivers in the box. That's the ideal way to measure drivers, in the box they'll be used, the results are more accurate than a simulated baffle response.
First up, the Frequence Response of both drivers measured at the same volume. These will be the traces I'll use for crossover simulations. The 165x is quite efficient, thanks to a light cone and strong motor. That means I won't have to pad the tweeter down much, which is always a good thing. Also note the 165x breakup that begins around 3300hz. One could probably use the driver with no notch filter, but I plan on implementing one in my design to tame the peak.

Here's the Impedance/Phase graph of the 165x in the sealed box. Of course the Fs will be significantly higher in a sealed enclosure. Hey Danny, what's up with that little squibble in the phase at 500hz that also shows in the frequency chart? Driver is NOT broken in.

Impedance/Phase of the XT25, driver not broken in. I plan on using a series resonance trap to tame the huge imp peak, nice low Fs!

M-165x CSD graph, again shows the breakup starting in the mid-3000hz range. I think it definately needs to be dealt with for ultimate performance.

Now to trace the curves for import into passive crossover designer and come up with an initial network attempt, and then of course lots of listening, measuring, and tweaking!