Hi Randy,
In my experience, power supply capacitors are always wired in parallel. I suppose somebody could make them in series, but I'm dashed if I can figure why they would want to.
Power supply capacitors are there to deliver "charge" (read: electrons) to the system, so that it will have the juice to work. Without the caps for storage - they are often called "reservoir capacitors" - the unit would have to run off the transformer alone, with no reserve for peak demand.
In series, the capacitance decreases (ex: 2 10K caps in series = 5k) and the resistive and inductive components of the caps simply add. This is bad all around as it 1: provides less capacitance for producing "charge", and 2: it makes more resistance and inductance to hinder the delivery of the charge that is available.
I hope I've made it a "newbie simple" explanation without taking to many tech liberties or "talking down" to you.
Cheers,
Dave