Hi newbie23,
Welcome to audiocircle and the RWA forum!
The Sig 30 and 70s have a small turn on pop (more like a higher frequency transient instead of a thump), but nothing that will come close to doing any damage to speakers... even 109dB speakers. Sure, you'll hear it more with 109dB speakers vs. 89dB speakers, but it still not powerful enough to damage your speakers.
Yes, I could have designed the output with a relay to wait for full power up before switching the speaker outputs on (and have actually tested a few of them during the prototype stage), but I have found that even high quality relays add some degradation (as well as adding a mechanical part) and I decided that the small turn on transient is minimal enough that it doesn't justify the use of a relay in the speaker output path.
Regarding the DACT, it is 20k (not 10k). I do not build the Sig 30 or Sig 70s without it. In theory, you could remove it but will will void the 5-year warranty.

Could I use a high quality 10k Caddock resistor in the signal path and bypass the DACT to use the TVC?
There would be no reason to do this, as the DACT is already very high quality. Use it to set the gain of the Sig 30 ("set it and forget it") that would allow you to obtain the most useable range out of your TVC, and use your TVC to control the volume. I do recommend that you also try simply using the DACT (without the TVC) to control the volume, as you will probably prefer the results of doing so over using the TVC in front of the Sig 30... especially if you are a purist as you mention.

I don't recommend using two passive volume controls (the TVC followed by the DACT) in the signal path. but feel free to experiment.
I know TVCs are nice and a lot of people like them, but you need to take my word that
the Sig 30 was voiced with the DACT in the input stage and you will throw off the tonal balance if you were to remove it. The Sig 30 and 70s use carefully selected parts that were not just chosen for their high quality and reliability, but were mainly chosen to give the sound that I was looking for... working together as a whole (a synergy of parts in the signal path, ie, "voicing the amp"). Most of this process was done via
listening, trial and error, tweaking, changing, refining, trying different combinations of parts, etc. It took a long time but it was well worth it!
Plus, using the Sig 30 would allow you to not need the TVC, so you could sell it aa
Best regards,
Vinnie