Interesting - I just posted a question to diyaudio along the lines of battery power UcD, although I was wondering about +-12 rather than 36. I'm not sure it's going to work, but might be worth trying.
I haven't really thought about switching for series/parallel for charging, but I'd be worried about sparking and inrush current. I get sparking even on my 12V setup when connecting the battery. I'd also worry a bit about running 6 in parallel - current imbalance might start to be a problem. The Solar guys seem to get uneasy with more than 3 in parallel, but then they're using much higher currents.
You might look into seeing whether there are chargers that use isolated outputs, which would allow stacking so you didn't have to rewire into parallel.