I've been interested in concrete for a while, and will be very interested in your results.
I have DIY concrete subwoofers and midwoofer cabinets in my uncompleted system right now. Despite my very amature efforts (3 of the 4 boxes ended up cracking) the sound seems quite good. Most people like the look of them too, even though they're just rough, unfinished concrete. These cabinets are way, way heavy!
The concrete can be textured and colored, so I'm sure it could be made to look great and fit any decore. If I had a place to do it I'd experiment more with this myself.
This is exciting stuff!