Bi-amping is a tricky subject. Using two identical amps to bi-amp will almost always sound better than using just one of those amps alone, but whether it will sound better than using a single amp with double the power output is much less certain. Whether it will sound sufficiently much better to justify the cost involved is even less certain - as a rule changes to the power amp have less effect per penny on the sound quality than changes to anything else, so long as the amp isn't actually clipping. You should usually spend money on upgrading the speakers, pre-amp, source, and room acoustics before thinking about the power amp.
The efficacy of bi-amping depends on what problem you're trying to solve. If what you're trying to do is prevent the different speaker elements from interacting with each other (e.g. a poorly damped woofer creating back-e.m.f across the mid-range and tweeter) then more electrical isolation is what's needed, and bi- or tri-amping will help.
If the problem is a lack of power then you may well be better off using a single, larger amp. The bass drivers use up most of the power. If we suppose that they use up 75%, using a single, 300W amp allows the bass drivers to suck up 225W. Switching to a pair of 300W amps only increases the bass power reserve to 300W. But switching to a single 600W amp lets them use 450W (and leaves more in reserve for the midrange and tweeters as well). So a single, high-power amp will probably be a better solution for correcting a lack of bass control, or any tendency to clipping in any of the drivers caused by a lack of power.
Which of these two problems is the more important to solve (lack of power/bass control, or poor driver isolation) varies from speaker to speaker. I've heard of people getting better results from bi- and tri-amping PMC speakers, and better results from using a higher-powered amp with B&W speakers, but that might just have been one particular model in each case.
Also bear in mind that a new, more powerful amp that also has lower distortion will probably help more than keeping the higher distortion amp and adding a second one.