Tony, using the 2496 in that way would invoke both the DAC and ADC stages of the Behringer, since it does its processing in the digital domain. Your analog input would be digitized for DSP manipulation, then converted back to analog for output to the amps.
For starters, I'd suggest feeding the 2496 with a digital signal from the S/PDIF output of the SB. That way, you avoid an DAC stage in the SB2 then an ADC stage in the 2496. Plus you don't have to mess around with the RCA-XLR converter.
Then, you could use the DACs of the 2496 to drive your amps. Or, for better sound, feed an external DAC with volume control (such as Benchmark DAC-1, Grace m902, or Stello DP200) from the digital output of the 2496. The analog outputs of the DAC would then drive the amps.
This approach will also give you a sweet headphone amp. The Grace in particular is an awesome DAC and a great headphone amp.