I was pretty big into industrial in my early college days but this was in hindsight as this was circa '93-94, which was technically post-industrial. My interest in industrial was motivated by NIN, Ministry, Skinny Puppy. I have many Front 242 albums, although none on vinyl.
I think one of the great colllections I have come across of industrial music was "Industrial Revolution: Vol II" (Vol I is basically the same volume but harder to come by) by Cleopatra Records. That spawned many further purchases. I was a fan of many Skinny Puppy/Ministry side projects.