I'll second the NHT active XO if you are doing a two way.
There are quite a few other active XO's to choose from other than the inexpensive Pro-Sound XO's. The vast majority of them are vintage (but don't let that scare you off).
Pioneer makes several models. All of them are from the 70's. Most of them were 3 way XO's that could be run in full range, 2 way or three way moses (they even made a 4 way XO). Their model numbers were (basically) the SF700, SF750, SF850 and the D23 and D24 (I might have missed one in there). These can be found every couple of months on eBay or Agon and the price varies by model but runs $250 (for the first SF700) up to as much as $800 for the D24.
Sony also made a 3 way XO back in the 70's. It was the TA 4300. In the past ten or so years, I've personally seen two of these, one of which I owned (and just recently sold). The ones I've seen sell for about $300 (good luck finding one though).
Audio Research made several different models. They were all tubed. They made 2 ways (EC2) and 3 ways (EC3). They varied between the years. Some of them had variable XO points, some didn't. The ones that didn't you had to swap resistors and caps to change the XO points. These sell for between $500 (EC2 fixed XO points) to $1200 (EC3).
Ron Wellborne just introduced an active 2 way XO kit. It's about $150 and uses an opamp. You need to add a power supply (a wall wart will work but something better is strongly seuggested). It looks to be a pretty nice unit. If I remember right, it has fixed XO points.
Several of the true high end mfgrs made XO's also. Naim, Levinson and others also either made or still make them but they are pretty pricey.
Now for the ProSound XO's. I'm not trying to start a flame war here, I'm only relaying my personal experiences in my systems (I've been either bi or tri amping for 6 years this last go around) (Oh, I used to do it back in the 70's too but that doesn't count in my books).
Now this is just my opinion, but I would stay away from these things in an 'audiophile' system. The reason I say this is first, I've tried several of these and they all sound dodgey at best. Pro Sound XO's (Behringer, DOD, Peavey, DBX, Ashley and others) typically perform WAY more functions other than being a basic XO. They do time delays for time alignment, low pass cut offs (subsonic), phase switches plus a host of other goodies (all of which vary by mfgr obviously).
All of these nifty gizmo's in the prosound XO's come with a sonic price. Each feature has it's associated electronics to make it work. More electronics usually means less sound. These prosound XO's typically use cheap opamps for gain stages. That is the last thing you want in a high resolution system. And finally, the XO points rather than being a decent multi-step switch with fixed resistors or caps, typically is a cheap pot.
As you can tell, I'm not a fan of the prosound XO's but thats just me. Lots of guys out there seem to like them. In my systems, I can hear them and I don't like the way they sound.
What I'm using now is the Pioneer SF750 in my high powered tube system and an AR EC-3 in my SET system. The Sony XO is more transparent than the Pioneers. Of the Pioneers, the SF 700 is the least transparent. I personally like the AR XO's but they are tubed (and I'm heavily tubed biased).
Knowing Ron Wellbornes ear, his little kit probably sounds way better than it should. The NHT is a similar design to Ron's and I'd bet (without actually hearing one) it sounds decent too.
Hope that helps.