My son has the Evo 4.4 towers and they sound great. Changing too much in the crossovers may ruin the sound. The speakers as is, sound fabulous.
I can see changing the 4 sandcast resistors to gain a little clarity. Also, switch out the binding post's to tube connectors will help with clarity. Otherwise you may not want to change much, especially for a center channel speaker that has been tuned for good TV audio.
We recently upgraded the crossover parts in a pair of PSB B6 speakers and completely changed the sound.
Also, that ribbon tweeter was tuned not to sound bright and harsh. You may ruin its sound with too many changes. Caps really do sound different.