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I have a Decware SE84UFO and Omega Alnico monitors and I'm using WE16GA, an old (WE stands for Western Electric) and simple tinned copper strand cable made famous on Positive Feedback writer Jeff Day's block. (jeffsplace@me.com) Can be hard to find, but it periodically shows up on eBay.Louis Chochos, the honcho at Omega, told me not to use heavy gauge cable. He thought Blue Jeans cable was OK, but advised against Anti-Cable.Day also recommends a relatively inexpensive interconnect made from Belden cable usually used for mics. Definitely check out his blog.
Power cords act as filters for noise created outside, but mostly inside your home, so question yourself on those points. Is there old/heavy industry sharing your substation (Deckert has that where he works/lives)? Old appliances, swimming pool/hot water pumps, ancient refrigerators on your transformer and/or electrical panel? Does your system sound better at times (random or late night)? If the answers to all this is no, then a new power cord will do little good.
Speaker cable isn't hard to figure out. The traditional standard is 12 gauge zip cord (lamp cord you can buy in bulk at hardware stores). Typical measurements for it are: resistance - Rdc: 3mohm/ft; inductance - Ls: 0.200uH/ft; and capacitance - Cp: 25pf/ft. Anything you buy should state those specifications and meet or exceed those numbers (lower the better). The best design is multiple smaller wire pairs running opposite in each pair. EMI shielding only a concern if you're near a HAM radio or are running parallel runs of speaker cable, if so 2 wire cables should be tightly twisted, multiple pairs should be spaced from each other. Silver plated connectors are a good choice - they don't oxidize. The dielectrics (insulation) should have low conductivity (air, loose cotton, air-filled polymers, or teflon).