Bruno Putzeys, Hypex and Grimm Audio designer, has mentioned that silver in teflon is a bad choice due to tribo electric effects. As he is not someone to espouse non-scientific "audiophile beliefs", I personally respect his opinion on this subject.
There is silver litz wire out there, which would entirely eliminate any worries about surface oxidation.
Insanely expensive Duelund silver wire in oil impregnated cotton is probably the "best" option, but the price...
I used to work for PS audio, and when we were developing new interconnect cables (which never actually made it to market) it came to our attention that silver wire of more than 4 nines was mostly myth. Yes, you could purchase wire which was nominally 5 nines, but when actually tested, not really. We found OCC copper to be at least as good, if not better, than the silver we could get. Inside a component, with multiple wire terminations, I would also expect termination type and quality would dominate sonic differences, and if you are talking about a preamp, which requires switching between mutiple inputs, the switch quality will probably make more difference than that between 4N/5N silver and OCC copper.