Nice purchase

There are a number of tweeters you could consider. Many folks have had luck pairing Hiquphons with Seas Excel drivers. On the used market you can find great deals on RAAL ribbons, SB Acoustic tweeters, Scan-Speak, etc. I suggest checking out the Parts Express forum (
http://techtalk.parts-express.com/) for good deals.
The two systems I am familiar with to test/design speakers would be OmniMic V2 (~$300) or REW (free) with a mic and preamp (~$125). There are a number of kind audio enthusiasts out there who will answer whatever questions you might have. Give it a shot

JohnR's advice was awesome. An active system is a great way to get started in my opinion. You can gain knowledge more quickly by measuring and adjusting things on the fly. There are numerous active crossover options available these days as well. I couple of the most popular are minidsp, Hypex's active modules, or a unit like the Behringer DCX2496.
Where are you located?