In my experience, the Front Wall/Rear Wall Floor/Ceiling seams are a good place for bass trapping. But not nearly as good as treating the corners of the room. Corner trapping was a major change in my room as well as rear wall trapping.
If you do not want to straddle a corner with a trap, you can put them flat on the wall to the left and right of the seam touching each other. I believe on Real Trap site they have a picture of this as an alternative to straddling the corner. I believe it came from a question about a door by the corner of the room. Cover the door and the wall next to it.
But your room is your decision, and compromises must be made in each of our rooms. Just know your bass trapping will not be as good as it can be.