With regard to your question, it depends on what input level the ADC accepts as full-scale input, and what the output level of the DAC is for full-scale. If they are the same, only then will you have unity gain. Otherwise, you don't. In either case, the volume control on the pre/pro will adjust volume, up to the point where you clip the ADC or reach full-scale output on the pre/pro.
You'd be better off with a digital signal from the pre/pro straight into the DAC though.