I don't have the Super V's, but I do have the V2's and I listen to classical music almost exclusively. I do think the V2's and super V's sound a lot alike, overall.
What makes these speakers special (IMO), is a sense of space, allied to a high level of clarity. What this means practically is that you get a better presentation of which parts of the orchestra are carrying on different musical lines. And, even more impressive - they are able to more clearly distinguish between groupings of instruments that normally just blend together - like a viola and a violin, for example.
To me, baroque music is highly emotional, but the performance must be good to bring that out. And even with a good performance, you must have great speakers to really appreciate it. I think the V series speakers definitely deliver on that.