Sam,
I'll have a go at this one......
I use a professional solder sucker. (This is a high end sex-aid for a pcb.....

)
These machines cost several hundred dollars; mine is a cheapie from Micron. You place the tip of the gun over the pad, with the hole centred on the end of the lead, and pull the trigger. It makes a dreadful noise, like a machine passing wind (the sonics of the expensive ones, like the Hako, are MUCH better!) The pad is heated, the solder removed, and minimal heat remains because it mostly comes off with the solder itself, and the pad has very low thermal inertia. This works well, and with care you can do this about ten times before the track/pad lifts.
Pcb tracks are held to the substrate with a special adhesive. This adhesive loses effectiveness with repeated application of heat.
The other way, not so wonderful, but the technique I used until about a year ago, is to go to Dick Smith Electronics (in Wellington) and buy a handheld manual solder sucker. This is about 15cms long, 2cms in diameter, with a large, spring-loaded piston inside. You set it against a little plastic stop, and when the nozzle is positioned over the molten solder joint (you need an iron, of course) you press the stop. The piston flies forward, creating low pressure at the joint, and the solder, now molten, flies up the nozzle, leaving the pad clean.
This technique heats the pad more, and you'll get maybe five applications only if you are good.
Pcbs are indeed perishable. It's a problem. But they've served the industry well, and I must admit I love to design them!
Cheers,
Hugh