Well, after much pulling out of my hair and substituting a iMac for the MacBook, I was further convinved that there was most definitely some very badly amiss.
Turns out that that just after I got my MacBook and before I got an external DAC, that I downloaded an equalizer application called "Hear" by daemon/joesoft. THIS was the culprit and even though I removed ALL files associated with it there was one hidden deep deep within a system folder and it was this plug-in that was causing the problem. I have since seen that others too have had the very same experience with this application.
I can NOW and only now hear the full glory of the Apogee DUET and it is simply STUNNING!
I just had to satisfy my curiosity as to how the Apogee MiniDAC was in comparison to the Apogee DUET, so I dropped into my dealer who by luck had a MiniDAC Demo unit. I said that I want to know how the two stood up against each other and his unhesitating answer was "DUET is better!" ..... but as we know, we need to hear this for ourselves, especially since this guy had not actually compared one against the other.
As it happens, this was a demo unit and he said that if I wanted I could do a straight swap against my new DUET. With that in mind, I was not swayed by the prices of the units - since effectively they would cost me the same, no matter which I choose.
Well, now after extensive and tortuous listening sessions with both I have come to a final conclusion. Both were level matched and each had similar VandenHul interconnect between DAC and my 300B S.E.T. amplifier The MiniDAC was connected by the USB connection and the DUET by Firewire.its XLR balanced outputs are far (way, way far) superior to its mini-jack 3.5mm outputs
The Apogee MiniDAC is most certainly an extremely good DAC, but in comparison to the DUET, the MiniDAC is slightly smaller scale and not as full bodied and a tad hard sounding at times.... a little clinical, very slightly mechanical and closed maybe. The DUET after that just opens up everything - HUGE sounding - wonderful wider soundstage with far better depth than the MiniDAC and vocals sound more natural. Phrasing and emotional expression is just easier to grasp with the DUET. Strings sounded like strings on the DUET, whereas on the MiniDac they were all there OK, but seemed smaller scale and thinner sounding.
I am totally convinced and happy with the DUET. For me, definitely better sounding than the MiniDAc - within the context of MY system and MY preferences.
When you read this, it may look like to you that there big differences between the two, but that in fact is not the case - what we are talking about here are minor, very minor changes in the presentation.
Just wanted to put things straight in case my post may have caused some to be swayed from the Apogee Duet..... the problem was nothing to do with the Duet, but it was my system that was at fault.
The integration, use and asthetics of the Duet with the Macbook is simply superb and works beautifully.
Thanks to everyone who took the time to read and or to post inn responce to my initial problem.
Regards
DerrO