I agree with AndyR that the biggest benefit of bi-amping is usually heard when going active. However, if your speakers are low sensitivity and would benefit from more grunt than your single amp can provide, then the extra headroom may well provide audible benefits.
I understand the temptation to go with different amps on tweeters and woofers. However, be very careful with this. Different amps, especially mixing tubes & SS, will have different sonic signatures, different tonality and different spatical characteristics. Without a lot of careful listening and/or luck, you may find that the different sonic signatures of the amps induce a discontinuity in the sound. For instance, some amps bring sounds forward more than other amps. If you use a more forward amp on one driver and a less forward amp on the other driver, then sounds from one driver may be recessed while sounds from the other driver are more forward, and sounds that have a frequency range that spans across the xo point (ie. reproduced by both drivers) will be somewhere in the middle and possibly not well focussed in a front to back sense. The tonal/timbral differences may also upset the timbral balance of such sounds, making the particular instrument sound a bit unnatural.