This piece of advice comes with all the usual caveats - at your own risk. You could hurt or kill yourself if you touch the wrong thing. I'm not liable for any damages to amp or your person etc.
Sucks I even have to say the above.
Anyway, you'll set the multimeter to DC. The probes will be placed on 4 and 5. Honestly doesn't matter which way. If you connect them one way, you'll get a positive reading. If you connect them the other way, you'll get a negative reading. Either way, if you just take the numerical value, you'll have your answer.
Good luck.