I'm sure there is improvement from high-end capacitors... normally I use 1% film caps in the tweeter signal path, so I'm not using crapacitors... but I'm probably not going all the way up to Mundorf Golds or Duelands either.
I've tried a bunch of them, and IME they are actually similar to wiring. The 2 most important things are dielectric and conductor.
Conductors - I find that copper is just a better conductor than tin or aluminum, so copper caps are almost always better than tin or aluminum caps.
Dielectric - Teflon is a better dielectric than polypropylene, and the paper/wax sounds best of all.
Resonance Control - One additional thing that is important with caps is resonance control. Which is why things like Clarity Caps sound so good - they do serious work to try to control resonance. But, the caps that do the most/best job at this are the paper/wax caps.
So based on these 3 criteria, Dueland and Jupiter are the best options. They both hit all 3 areas - conductor, dielectric and resonance control are all excellent. Between the 2, IMO Dueland is not really any better than the Jupiters.
So there you go, my wholehearted endorsement for Jupiter Copper Paper/Beeswax caps
