I'm curious if I need anything on the back wall, centered between the speakers?
To most of us, the back wall is the wall behind
you, the listener. That wall needs treating much more than the front wall behind the speakers, especially if it's closer than ten feet behind you. Sound from the speakers goes past your head, hits the rear wall, then comes back at you. If you add absorption or diffusion on the wall behind you, less energy comes back to you and toward the front wall. That's why the rear wall makes more sense for treatment. More here if you care:
Front Wall AbsorptionI'll add that reflections from the side walls are also more damaging than from the front wall, so that's another place to consider absorption.
--Ethan