The Radian coax's I posted early and ooheadsoo reposted are expensive, but they are most likely worth it. These are the same drivers used in some very well reviewed speakers. They are decently high efficiency which is always good too. They come with apparently a damn good xo and hard to top. If I had room to mount inwalls (my walls are plaster over brick) I'd use these. As it is, I am using a design from htguide.com for onwalls instead.
You could conceivably use them as on walls...not real BSC change is needed, maybe a diffraction change, but probably not. However, I think they are too deep for most on wall applications. As it is with in wall you will likely need to mount the xo differently than pictured.