That's something ive been curious about as well, esp after the whole drama with Audio Science Review reviewing the XLS kit, but doing a bare minimum assembly, Without polyfill/norez, no round overs on the edges etc.
It measured well, and got an overall positive review, but wasnt an entirely fair representation as it was essentially a "bare-bones" worst case scenario, which considering the positive review regardless, should be a testament to Danny's skill and knowledge.
However, the drama really arose from the ASR guys making fun of using high-quality components; namely tube connectors & bypass caps. Essentially saying that "if it's not measurable, it doesn't exist"
IMO, Im sure that there is a way to measure it electrically, but will require more sophisticated, sensitive & expensive tools than any average person will likely ever have on hand.
If there is an audible difference to your ears, it exists. (In my experience, there is definitely a difference, but how noticable it is will likely depend on your gear & the quality of the recording.)
But it would be interesting to find out the best way to measure the differences that aren't noticeable from typical measurement graphs.