I've only compared the PS Audios to other cables in a showroom, not at home. In the showroom, they were compared to Kimber, Audioquest, and Transparent. I do not care for any of those. As always, those are to my ears. YMMV.
What I like about the PS Audios is that (as with many cables) you can try them out for 30 days and return them if you're not down with them. Since they're on sale, it's hard to be beat!
I think you just have to listen to them to see if you like them. I've turned a lot of my friends on to them and they've all stuck with them. One even ditched all his other cables (many different brands) and went all PS Audio.
I did go with the Plus XLRs because the Statements were way too thick.