AudioQuest has some basics on biwiring at
http://www.audioquest.com/. Select Cable Theory and go to p. 5.
I believe in biwiring and use 2 different double biwires for my 3 fronts. For the 2-way Kindel PLS-A L/Rs, I use KE-6[8]* on the bass/MR and KE-4 on the treble. On the 3-way Aerial CC3B center, I use KE-6[8] on the MR/treble and very inexpensive Type 6 on the bass. I'm absolutely convinced that the best silver conductors sound better than the best copper conductors, and I spent my money that way.
The rears are double-biwired with AQ's Bedrock, 32 and 36 feet.
* KE-6 (and CV-6, too) is now 8-conductor instead of 6-, but they haven't yet renamed them.