Tom -
For a normal rear-ported speaker, being that close to the rear wall would be somewhat problematic. But we have found that the SongTowers with their transmission line cabinet work quite well that distance from the rear wall. The closer you get to the rear wall, the more bass reinforcement you will get. But at a certain point, it will tend to sound a little "boomy".
As for the side walls, this is an issue where room treatments of some sort can help quite a bit. The problem is, sound coming from the speakers is reflected off the wall from the first reflection point. (Have someone slide a mirror along the wall while you are seated in the listening position. When you see a reflection of the speaker in the mirror, that is a reflection point. Remembering back in your school days, the angle of incidence equals the angle or reflection.)
The problem is, these reflections arrive at your ears very shortly, time-wise, after sound arriving directly from the speaker. The time differential is so minimal, your brain does not recognize the reflection as a reflection. It interprets this reflected sound as coming directly from the speaker. So the reflections from close surfaces tend to smear the image.
About the only solution is to have some absorptive material at that first reflection point to kill the reflections. This is a very inexpensive system upgrade and can produce impressive results.
Acoustic panels can be home made. Or you can purchase them. In fact, companies like GIK can produce panels with photographs or artwork - even your own photos. This can increase SAF/WAF.
As for toe-in, SongTowers really don't require any as their off-axis response is excellent. But you can certainly experiment with it. The more you toe the speakers in, the more precise the center image will become. But the sound stage will not be quite as wide. So it is a matter of trading off imaging for sound stage width. Play with toe-in until you find the amount that works best for you. This will vary by individual and there really is no right or wrong.
I hope this helps.
- Jim