I actually thought about that also. I do know the amp is not balanced and it's "overkill" but I will be running RCAs to the sub I purchased from Danny. Reason why I am looking for XLR to connect the DAC and Amp. I am wanting to buy local and Cardas Audio is well known and respected and it's here in my home state of Oregon and I live within driving distance from an authorized audio store.
I built my audio system around the thought I want to buy American made and if possible local.
Well, I'd prioritize the main amp, so the right answer to this really depends on what PSA recommends. You should also ask them if grounding pin3 directly on the XLR out will be ok, because that's what the Odyssey amp will do, at least the one I have does this, I can't speak for all of them... If they tell you that both outs are the same, this is pretty much impossible, it costs $$$ to have both be of similar quality, so ask them if the output is natively balanced or single ended and use that one for the main amp. Electronics are going to be primarily single ended or balanced, and if they have both outputs often the non-native output is compromised. So, you don't want to send the best output to the sub and an inferior output to the main amp! It's possible the sub amp will ground pin3 as well if it has XLR ins.
If PSA says it's single ended and it doesn't have 2 RCA outputs, and the sub amp doesn't have XLR inputs, the choices are use a RCA cable splitter, an XLR > RCA converter on the XLR outs, or get a cable that goes from XLR > RCA.
I know this is more complicated that you may have expected, but this is what we have to deal with when we have a mix of balanced and single ended components out there. IMO, we should have left balanced for pro gear, it's just an unnecessary expense and complication for home audio. Others will have different opinions based on past experience, but it's rarely valid... most folks have no issue with single ended audio systems being noisy, and if they do the issue is even more rarely the "need" for balanced gear to reject noise.