Carlos,Yep, I have, on a DIY three-way speaker. I started off with all of the components in the enclosure,except for a .25mH Goertz inductor which was mounted on the outside where it could be wired directly across the free standing planer magnetic tweeter. Everything else was in the enclosure. I then moved everything outboard when I upgraded all of the caps in the system to Hovland caps and replaced the 3mh coil on the midrange with another Goertz inductor.
It was a lot easier to play with the crossover to optimize it for the F6 midrange driver which replaced a Lineaum dipole midrange driver with everything outside the enclosure. Wiring point to point inside the enclosure was a bitch the first time and I still have some scars from trying to solder inside the hole where the woofer mounted. There was a steep learning curve where I figured out that soldering point to point inside the box was a dumb idea the first time around.
I think eliminating the xover circuit board,mounting the parts on a wooden board and wiring point to point may be a bigger possible improvement
than placing the xover outside the enclosure. The theory goes that the parts themselves may microphonic in some cases and moving them away from a major source of vibration could yield an audible improvement.
A single blind test would be easy enough to do but the results, positive or negative, would be specific to a particular pair of loudspeakers and the crossover parts used and could not be construed to support a generalized rule of thumb one way or another. Another good test would be to thump on the capacitor connected to the tweeter while a piece of music is playing and see
if you can hear if it modulates the signal going to the tweeter. If you can't hear anything thing you don't have a problem.
Scotty