Staright from NuPrime DAC-10H's manual:
Inputs:
• 1 x USB Digital
• 2 x Coaxial Digital S/PDIF
• 2 x Optical Digital S/PDIF
• 2 x Analog Stereo RCA
Outputs:
• Stereo RCA (Line out)
• Stereo Balanced (XLR-3 socket pre-out )
• Balanced headphone amplifier (XLR-4 socket )
• Unbalanced headphone amplifier (6.3 mm jack socket )
• USB Sampling Rates: 44.1KHz, 48KHz, 88.2KHz, 96KHz, 176.4KHz, 192KHz, 352.8KHz, 384KHz and DSD 2.8MHz (DSD64) , 5.6MHz (DSD128) 11.2MHz (DSD256)
• S/PDIF Sampling Rates: 44.1KHz, 48KHz, 88.2KHz, 96, 176.4KHz, 192KHz
As you can see, both Coax and Optical are S/PDIF and can do sample rates up to 192KHz. USB can sample up to 384KHz and also DSD up to DSD256 (11.2MHz). Coax is better than Optical because the digital signal is being sent straight out of the player to the DAC for decoding while Optical requires being converted to send across the line and unconverted back to the digital signal prior to being received by the DAC.
According to EJ Sarmento, the genius audio engineer behind Wyred 4 Sound and SST, the original reason that he developed the Remedy unit was because the only output from many Apple units was Optical and it was so poor. The Remedy was developed to solve this problem and then later Coax re-clocking was added to the unit to give some improvements on this end also. But he highly recommends using Coax versus Optical if you have the option to do this. EJ told me this as when he was explaining why you should also use Coax over Optical if your gear supports it (ps... I live near him).