Yes, the connector block on the back is for daisy-chaining.
Many devices will allow the polarity to switch, meaning it doesn't matter which wire you put where. I don't know off-hand how Bryston is, but if you check the manual, it should state.
If you want to be precise (as I prefer), the source component should specify if the tip or the sleeve is positive or negative. Then, match that to Bryston's specification.
Usually, the sleeve is the ground and the tip is the signal or positive. A simple electrical meter can tell you which is which when you strip the wire. Odds are the tip wire will be independently insulated where the ground/sleeve will be bare.
- Garrett